期刊
CHEMISTRY LETTERS
卷 42, 期 9, 页码 980-982出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130338
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology [24350026]
- Grants-in-Aid for Scientific Research [11J09109, 24686091] Funding Source: KAKEN
In the presence of a simple combined catalyst of a tungstate monomer (TBA(2)WO(4), TBA: tetra-n-butylammonium) and rhodium acetate (Rh-2(OAc)(4)), hydrosilylation of various types of substances including ketone, aldehyde, carbon dioxide, alkene, nitrile, and furan derivatives efficiently proceeded, affording the corresponding hydrosilylation products in moderate to high yields (>= 63% yields). In addition, the present system was also applicable to the one-pot reduction of benzamide to benzylamine (95% yield).
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