期刊
CHEMISTRY LETTERS
卷 40, 期 7, 页码 750-752出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.750
关键词
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资金
- Ministry of Economy, Trade and Industry
A coin cell battery is fabricated using triquinoxalinylene as a cathode active material and a lithium metal anode. The first discharge curve shows a remarkably large capacity (420 A h kg(-1)), which corresponds to a six electron migration in the first charge. However, repeating the charge-discharge until the 15th cycle gradually decreases the capacity, but after that the capacity remains constant with a value of 220A h kg(-1). This large value remains even after 100 cycles. Additionally, the use of a tribromo-substituted derivative gives a large discharge capacity (approximate to 250 A h kg(-1)) due to a comparatively stable six electron migration from the first charge-discharge cycle.
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