期刊
CHEMISTRY LETTERS
卷 39, 期 9, 页码 978-979出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.978
关键词
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资金
- MEXT, Japan [21108006]
- Grants-in-Aid for Scientific Research [21108006] Funding Source: KAKEN
A cyanide-bridged molecular square, [Co2Fe2(CN)(6)(tp*)(2)-(dtbbpy)(4)](PF6)(2)center dot 2MeOH (1) (tp* = hydrotris(3,5-dimethylpyrazol-1-yl) borate and dtbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine) was prepared by the reaction of (Bu4N)[Fe(CN)(3)(tp*)] with Co(CF3SO3)(2)center dot 6H(2)O and dtbbpy in methanol. Variable temperature X-ray structural analyses, magnetic and spectroscopic data revealed that 1 exhibited novel thermal two-stepped spin transitions induced by intramolecular electron transfers.
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