期刊
CHEMISTRY LETTERS
卷 39, 期 3, 页码 190-191出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.190
关键词
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资金
- National Natural Science Foundation of China [20721001]
- MSTC [2007CB815301]
- National Science Fund of China for Fostering Talents in Basic Science [J0630429]
A metastable 3D supramolecular compound [Ag(NH3)(2)]-[Ag-3(pzdca)(2)(NH3)(4)] (H(2)pzdca = pyrazine-2,3-dicarboxylic acid) (1) has been synthesized and characterized crystallographically. This study offers important information to in-depth understanding of the self-assembly process involving Ag-1 under ammoniacal conditions and conforms that [Ag(NH3)(2)](+)-containing compounds are the intermediates during synthesis of some Ag-1 coordination polymers.
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