期刊
CHEMISTRY LETTERS
卷 39, 期 6, 页码 556-557出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.556
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资金
- Grants-in-Aid for Scientific Research [22550124] Funding Source: KAKEN
We have synthesized and characterized a new G G mismatch binding ligand containing a TEMPO radical. The two mismatch binding ligands cooperatively bound to the CGG/CGG triad and an apparent binding constant was in the order of 10(5)M(-1). The tumbling of the ligand on a DNA duplex was ten times slower than that of the unbound ligand. Asymmetric addressability of two TEMPO radicals on DNA is shown.
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