期刊
CHEMISTRY LETTERS
卷 38, 期 5, 页码 434-435出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.434
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan. [17205008, 18002016]
- Grants-in-Aid for Scientific Research [18002016, 17205008] Funding Source: KAKEN
An air-stable dinuclear iron-dithiolene complex with an Fe-2(mu-S)(2) core, [Fe-III(mnt)(2)](2)(2-) (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH3CO2H, has been found to serve as a major proton mediator during the electrocatalytic tic hydrogen evolution.
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