期刊
CHEMISTRY LETTERS
卷 37, 期 12, 页码 1296-1297出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.1296
关键词
-
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT)
- Okayama Prefecture Industrial Promotion Foundation
- Electric Technology Research Foundation of Chugoku
- Tokuyama foundation
Nucleophilic addition of RLi to a triple bond of dibenzocycloocta[a,e]diyne provides dibenzo[b,f]pentalene motif through trans-annulation of the resulting vinyllithium. Dibenzopentalene anion thus formed reacts with various electrophiles such as aldehydes, alkyl halides, acid halide, and Me3SiCl to give the corresponding products.
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