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Low Melting and Electrochemically Stable Ionic Liquids Based on Asymmetric Fluorosulfonyl(trifluoromethylsulfonyl)amide

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CHEMISTRY LETTERS
卷 37, 期 10, 页码 1020-1021

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CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.1020

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  1. METI
  2. NEDO

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An asymmetric amide anion, FTA(-) {[(FSO2)(CF3SO2)-N](-)}, has a significant ability to reduce the melting points of an aliphatic quaternary ammonium salts even for a symmetric tetraethylammonium. Much more interestingly, the electrochemical stability of this anion was comparable to a typical amide anion, such as bis(trifluoromethylsulfonyl)amide.

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