期刊
CHEMIE INGENIEUR TECHNIK
卷 83, 期 1-2, 页码 90-103出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cite.201000188
关键词
Asymmetric catalysis; Chiral; Coordination polymer; Metal-Organic Framework; Porous materials; Stereoselective separation
The targeted synthesis of a desired stereomer plays a key role in life sciences, especially in the production of drugs. Up to date, this area is dominated by homogeneous chiral catalysts. Metal-Organic Frameworks (MOFs), a new class of porous materials, consisting of metal-oxo-clusters and multifunctional ligands could offer a platform for chiral heterogeneous catalysts combining the efficiency and in particular selectivity observed for homogeneous asymmetric catalysts with the advantages of heterogeneous catalysis. This review summarizes strategies to obtain chiral Metal-Organic Frameworks and gives an overview about reactions that have been successfully conducted using chiral MOFs as asymmetric catalysts. In addition, some examples highlighting the stereoselective adsorption properties of chiral Metal-Organic Frameworks are given.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据