4.8 Review

MOF positioning technology and device fabrication

期刊

CHEMICAL SOCIETY REVIEWS
卷 43, 期 16, 页码 5513-5560

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00089g

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资金

  1. CSIRO OCE
  2. Australian Research Council [DE120102451, DE140101359]
  3. Australian Research Council [DE120102451, DE140101359] Funding Source: Australian Research Council

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Metal organic frameworks (MOFs) offer the highest surface areas per gram of any known material. As such, they epitomise resource productivity in uses where specific surface area is critical, such as adsorption, storage, filtration and catalysis. However, the ability to control the position of MOFs is also crucial for their use in devices for applications such as sensing, delivery, sequestration, molecular transport, electronics, energy production, optics, bioreactors and catalysis. In this review we present the current technologies that enable the precise positioning of MOFs onto different platforms. Methods for permanent localisation, dynamic localisation, and spatial control of functional materials within MOP crystals are described. Finally, examples of devices in which the control of MOF position and functionalisation will play a major technological role are presented.

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