期刊
CHEMICAL SOCIETY REVIEWS
卷 43, 期 18, 页码 6639-6657出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cs00019f
关键词
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资金
- Fonds der Chemischen Industrie (FCI)
- German Science Foundation (DFG) [WE 4621/2-1]
- ERC [SynPhos 307616]
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-) phosphorus compounds and materials of added value.
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