期刊
CHEMICAL SOCIETY REVIEWS
卷 43, 期 8, 页码 2799-2823出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cs60343a
关键词
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资金
- NSFC [21371036, 91122017]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1117]
- Fundamental Research Funds for the Central Universities [20520133030]
- Shanghai Rising-Star Program [11QA1400300]
Half-sandwich Cp*Ir and Cp*Rh metalacycles have been successfully applied in traditional domains encompassing organic transformations and catalysis in recent years, especially the catalytic activation of C-H bonds. Cyclometalation has proven to be a highly attractive and versatile synthetic method for the formation of organometallic metalacycles. This review intends to describe isolated and well-defined cyclometalated iridium/rhodium complexes that contain a Cp*M-C (M = Ir, Rh) bond stabilised by the intramolecular coordination of neutral donor atoms (N, C, O or P). The formation of metalamacrocycles and cages employing cyclometalated approaches is discussed. In focusing on selected mechanistic insights garnered from iridium/ rhodium-catalysed functionalisation of C-H bonds involving cyclometalated complexes, a limited number of substrates will be discussed, but a broad range of mechanistic features is highlighted.
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