期刊
CHEMICAL SOCIETY REVIEWS
卷 42, 期 24, 页码 9480-9508出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cs60261c
关键词
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资金
- National Natural Science Foundation of China [21302026, 21272045, 21361006]
- Natural Science Foundation of Guizhou Province
Cucurbit[n]urils are a family of molecular container hosts bearing a rigid hydrophobic cavity and two identical carbonyl fringed portals. They have attracted much attention in supramolecular chemistry because of their superior molecular recognition properties in aqueous media. This review highlights the recent advances and challenges in the field of cucurbit[n]uril-based coordination chemistry. It not only presents progress in the knowledge of such macrocyclic compounds, which range from simple to complicated architectures, but also presents new routes of synthesis and their advantages in hybrid porous solids. The concept of structure inducer for their structural design to achieve predictable structures and controlled pores is described. The large pore sizes and hydrophobic cavities of these compounds that lead to unprecedented properties and potential applications are also discussed.
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