期刊
CHEMICAL SOCIETY REVIEWS
卷 42, 期 18, 页码 7668-7700出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cs35526h
关键词
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资金
- National Natural Science Foundation of China [20772117]
- Knowledge Innovation Project of the Chinese Academy of Sciences [KJCX2.YW.H16]
- Key Project of Science and Technology of the Department of Education, Anhui Province, China [KJ2010ZD05]
Recently, mechanical milling using a mixer mill or planetary mill has been fruitfully utilized in organic synthesis under solvent-free conditions. This review article provides a comprehensive overview of various solvent-free mechanochemical organic reactions, including metal-mediated or -catalyzed reactions, condensation reactions, nucleophilic additions, cascade reactions, Diels-Alder reactions, oxidations, reductions, halogenation/aminohalogenation, etc. The ball milling technique has also been applied to the synthesis of calixarenes, rotaxanes and cage compounds, asymmetric synthesis as well as the transformation of biologically active compounds.
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