期刊
CHEMICAL SOCIETY REVIEWS
卷 41, 期 23, 页码 7673-7686出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cs35242g
关键词
-
资金
- EPSRC
- ERC [FCC 266804]
- EPSRC [EP/I010319/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/I010319/1] Funding Source: researchfish
Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide ions are ideally suited for CPL spectroscopy and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis. The perturbation of a dynamically racemic complex may occur either by a change in complex constitution or by non-covalent association. With complexes of enantiopure ligands, perturbation may involve either dynamic helicity inversion or a reversible change in the lanthanide coordination environment.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据