期刊
CHEMICAL SOCIETY REVIEWS
卷 41, 期 22, 页码 7335-7353出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cs35145e
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资金
- Centre National de la Recherche Scientifique (CNRS)
- Ministere de l'Education Nationale de l'Enseignement Superieur et de la Recherche (MENESR)
- University of Versailles Saint Quentin
The present tutorial review reports on the synthetic approaches for the formation of polyoxothiometalate compounds with special emphasis on the unique reactivity of the preformed sulfur-containing cationic building blocks {Mo2O2S2}(2+) and {Mo3S4}(4+) toward polyoxometalate building blocks. Such simple chemical systems, based on chemical and structural complementarities between ionic reactive moieties have led to the synthesis of a series of relevant clusters with unrivalled large nuclearity structural arrangements, such as loops, triangles, squares and boxes. Specific reaction parameters and considerations will be pointed out showing that a deliberate pure inorganic supramolecular chemistry based on weak interactions, flexibility and dynamic is possible with polyoxometalates.
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