期刊
CHEMICAL SOCIETY REVIEWS
卷 38, 期 11, 页码 3133-3148出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b901177n
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资金
- NIGMS NIH HHS [R01 GM077379] Funding Source: Medline
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM077379] Funding Source: NIH RePORTER
Among the fundamental chemical transformations in organic synthesis, the [3,3]-sigmatropic rearrangement occupies a unique position as a powerful, reliable, and well-defined method for the stereoselective construction of carbon-carbon or carbon-heteroatom bonds. While many other reactions can unite two subunits and create a new bond, the strengths of sigmatropic rearrangements derive from their ability to enable structural reorganization with unmatched build-up of complexity. Recent applications that illustrate [3,3]-sigmatropic processes as a key concept in the synthesis of complex natural products are described in this tutorial review, covering literature from about 2001 through early 2009.
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