期刊
CHEMICAL SOCIETY REVIEWS
卷 38, 期 11, 页码 3193-3207出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b821092f
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资金
- National Science Foundation [CHE-0911713]
- National Institutes of Health [CA-109164]
- Sanofi-Aventis
- Novartis
- Division of Organic Chemistry of the American Chemical Society
- NATIONAL CANCER INSTITUTE [R56CA109164, R01CA109164] Funding Source: NIH RePORTER
This tutorial review highlights the use of catalytic asymmetric 2-naphthol couplings in total synthesis. The types of chirality, chiral biaryl natural products, prior approaches to chiral biaryl natural products, and other catalytic asymmetric biaryl couplings are outlined. The three main categories of chiral catalysts for 2-naphthol coupling (Cu, V, Fe) are described with discussion of their limitations and advantages. Applications of the copper catalyzed couplings in biomimetic syntheses are discussed including nigerone, hypocrellin, calphostin D, phleichrome, and cercosporin.
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