期刊
CHEMICAL SOCIETY REVIEWS
卷 38, 期 8, 页码 2282-2291出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b806837m
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资金
- NSERC Canada
- Petroleum Research Fund
The conventional homogeneous catalysts for the enantioselective hydrogenation or transfer hydrogenation of ketones are based on platinum metals and, in particular, ruthenium. This method provides valuable enantiopure alcohols for the fine chemical industries. This tutorial review summarizes recent successes in replacing expensive and toxic ruthenium in these catalysts with greener'' iron substitutes including my lab's recent progress in this area using iron complexes containing readily-prepared tetradentate ligands. It will enlighten chemists interested in homogeneous catalysis and asymmetric synthesis.
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