期刊
CHEMICAL SOCIETY REVIEWS
卷 38, 期 11, 页码 3102-3116出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b816700c
关键词
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资金
- US National Science Foundation [CHE-0848224]
Lewis base catalysis of reactions with allenoates using phosphine and amine nucleophiles has emerged as a key platform for the generation of molecular complexity. Investigations in this area have established a range of suitable coupling partners for allenoates, including electron-deficient olefins, imines, and aldehydes. This tutorial review will describe these methodologies, with a special emphasis on recent work regarding asymmetric reactions using chiral Lewis base catalysts.
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