期刊
CHEMICAL SOCIETY REVIEWS
卷 38, 期 8, 页码 2190-2201出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b817310a
关键词
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资金
- National Natural Science Foundation of China [20732006, 20821002]
- National Basic Research Program of China [2009CB825300]
- Chinese Academy of Sciences
- Science and Technology Commission of Shanghai Municipality [07pj14106, 07JC14063]
The asymmetric Friedel-Crafts reaction is one of the most powerful methods to synthesize optically active aromatic compounds. Particularly, the Friedel-Crafts alkylation of arenes with unsaturated compounds activated by chiral Bronsted acids provides direct access to enantiopure aromatic derivatives with perfect atom economy. In this tutorial review, recent progress in the development of chiral Bronsted acid-catalyzed asymmetric Friedel-Crafts reactions is presented.
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