期刊
CHEMICAL SOCIETY REVIEWS
卷 37, 期 10, 页码 2224-2242出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b718768h
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资金
- German Science Foundation through Sonderforschungsbereich
- Deutsche Forschungsgemeinschaft
- European Community
- Fonds der Chemischen Industrie
- Italian MIUR
- European GSOMEN Project
- Alexander von Humboldt Foundation
Ultrathin oxide films on metals offer new opportunities for the design of supported nanoclusters with potential use in catalysis. This requires a characterization at the atomistic level of the structure and composition of the thin film, of its morphology and defect structure. A proper selection of metal/oxide interface, film thickness, lattice mismatch, etc. makes it possible to prepare collections of supported metal particles with novel properties. This critical review describes some illustrative examples, emphasizes the role of the interplay between theory and experiment, and relates some recent findings related to the possibility to control the charge state of a supported nanoparticle on an ultrathin oxide film (211 references).
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