期刊
CHEMICAL RECORD
卷 15, 期 1, 页码 31-51出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201402081
关键词
bioactive molecules; click chemistry; fullerene; photochemistry; synthetic methodology
资金
- University of Strasbourg
- CNRS
- Agence National de la Recherche Scientifique (ANR)
- International Center for Frontier Research in Chemistry (icFRC)
- LabEx Chimie des Systemes Complexes
Click reactions largely cross the borders of organic synthetic chemistry and are now at the forefront of many interdisciplinary studies at the interfaces between chemistry, physics, and biology. As part of this research, our group is involved in a program on the development of clickable fullerene building blocks and their application in the preparation of a large variety of new advanced materials and bioactive compounds. Importantly, the introduction of the click chemistry concept in fullerene chemistry allowed us to produce compounds that would barely be accessible by using the classical tools of fullerene chemistry. This is particularly the case for the conjugation of fullerenes with other carbon nanoforms, such as carbon nanohorns and graphene. It is also the case for most of the sophisticated molecular ensembles constructed from clickable fullerene hexa-adduct building blocks. In this paper, we have summarized our ongoing progress in this particular field.
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