期刊
CHEMICAL RECORD
卷 13, 期 1, 页码 28-42出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201200010
关键词
asymmetric catalysis; enantioselectivity; helical structures; organocatalysis; pyridines
资金
- National Science Foundation [CHE-1152850]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1152850] Funding Source: National Science Foundation
A new family of chiral pyridines has been designed and synthesized for use in asymmetric organocatalysis. Thus, helical-chiral pyridines induce high enantioselectivity in a range of mechanistically unrelated, synthetically significant transformations, including Friedel-Crafts alkylation with nitroalkenes, periselective Diels-Alder reactions with nitroalkenes, the ring-opening of epoxides with a chloride nucleophile, and the propargylation of aldehydes. DOI 10.1002/tcr.201200010
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