期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 4, 页码 1523-1526出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509548
关键词
enantioselectivity; homogeneous catalysis; hydrogen-atom transfer; radicals; titanium
资金
- DFG [SFB 813]
- Alexander von Humboldt-Stiftung
- Jurgen Manchot Stiftung
- Regional Government of Andalucia [P12-FQM-790]
Two new catalytic systems for hydrogen-atom transfer (HAT) catalysis involving the N-H bonds of titanocene(III) complexes with pendant amide ligands are reported. In a monometallic system, a bifunctional catalyst for radical generation and reduction through HAT catalysis depending on the coordination of the amide ligand is employed. The pendant amide ligand is used to activate Crabtree's catalyst to yield an efficient bimetallic system for radical generation and HAT catalysis.
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