期刊
CHEMICAL PHYSICS LETTERS
卷 535, 期 -, 页码 126-130出版社
ELSEVIER
DOI: 10.1016/j.cplett.2012.03.070
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资金
- MESA+ Institute for Nanotechnology of the University of Twente
- Netherlands Organization for Scientific Research (NWO) [700.56.322,]
The molecular stretching behavior of temperature responsive poly(N-isopropylacrylamide) (PNIPAM) chains was studied by atomic force microscopy based single molecule force spectroscopy. Force-extension curves obtained in water below and above the lower critical solution temperature, in the co-nonsolvent water/methanol mixture, and in dimethyl sulfoxide (H-bond blocking) follow the same trajectory, independently whether the chain was pulled from a collapsed or from a solvated state. This result indicates that for a single PNIPAM chain the formation of intrachain H-bonds in the precipitated state does not cause measurable chain stiffening at the single chain level. (C) 2012 Elsevier B. V. All rights reserved.
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