期刊
CHEMICAL PHYSICS LETTERS
卷 514, 期 1-3, 页码 168-173出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2011.08.030
关键词
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We present the first N-14 overtone NMR spectra obtained directly under magic angle spinning conditions. Line-broadening contributions from chemical shift anisotropy and heteronuclear dipolar couplings are significantly reduced, and, despite theoretical predictions, spinning sidebands are minimal, leaving second-order quadrupolar powder patterns with narrow discontinuities that can be observed using a single excitation pulse. We also show that the limited bandwidth and offset-dependent nutation rates exhibited by standard RF pulses can be overcome using frequency-swept pulses, allowing the direct acquisition of solid-state N-14 NMR spectra in which multiple nitrogen sites are well-resolved. Crown Copyright (C) 2011 Published by Elsevier B. V. All rights reserved.
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