期刊
CHEMICAL PHYSICS LETTERS
卷 497, 期 1-3, 页码 7-11出版社
ELSEVIER
DOI: 10.1016/j.cplett.2010.07.086
关键词
-
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
Model chemistry calculations (CBS-QB3 and CBS-APNO methods) and tandem mass spectrometry based experiments indicate that dissociative ionization of 2-methoxy-s-triazine (consecutive losses of CH2O and HCN) yields the elusive covalently bound [H,C,N] dimer ion HC=N-C=NH center dot+, a species of interest in astrochemistry. Neutralization-Reionization Mass Spectrometry (NRMS) experiments indicate that its neutral counterpart, HC=N-C=NH, is a kinetically stable molecule in the rarefied gas-phase. (C) 2010 Elsevier B.V. All rights reserved.
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