期刊
CHEMICAL PHYSICS LETTERS
卷 495, 期 4-6, 页码 222-227出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2010.06.087
关键词
-
资金
- National Basic Research Program of China [2007CB815203]
- NSFC [20573097, 20803066, 20703038]
- NSFZ [R405465, Y409016]
The A- and B-band resonance Raman spectra of Cu(II)-bisacetylacetone in methanol solution were obtained and their intensity patterns were found to be significantly different. It appears that the A- band structural dynamics is mostly along the photophysically and photochemically important C(gamma)C(beta)/C(beta)C(alpha) and Cu-O stretch reaction coordinates, while the B-band structural dynamics is mainly along photochemically important Cu-O stretch reaction coordinate. The significantly different structural dynamics provide an evident that the primary photoreduction reactions of Cu(II)-bisacetylacetone are wavelength dependence. (C) 2010 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据