4.6 Article

Infrared spectra of zinc and cadmium dioxide anions in solid neon

期刊

CHEMICAL PHYSICS LETTERS
卷 489, 期 4-6, 页码 181-186

出版社

ELSEVIER
DOI: 10.1016/j.cplett.2010.02.077

关键词

-

资金

  1. National Basic Research Program of China [2007CB815203]
  2. National Natural Science Foundation of China [20773030]

向作者/读者索取更多资源

Zinc and cadmium dioxide anions are produced via electron capture of the corresponding neutral molecules during condensation of laser-ablated zinc and cadmium atoms with O-2 in excess neon at 4 K. Photosensitive infrared absorptions at 624.1 and 483.6 cm(-1) are assigned to the antisymmetric stretching vibrations (nu 3) of the linear ZnO2- and CdO2- anions on the basis of isotopic shifts and splittings as well as density functional calculations. The predicted quite low nu(3)/nu(1) ratios for both anions with (2)Pi(g) ground state are similar with the valence isoelectronic CO2+ and BO2 molecules. (C) 2010 Elsevier B. V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据