期刊
CHEMICAL PHYSICS LETTERS
卷 484, 期 4-6, 页码 387-391出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2009.11.046
关键词
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资金
- National Natural Science Foundation of China [10774103]
- Education Ministry of China [20050610011]
Using the unified ligand-field coupling scheme, the local structures and optical spectra of octahedral Fe3+ centers in a series of garnet crystals have been investigated systematically with two different values of parameter A(4). Our results show that the local structures of octahedral Fe3+ centers in doped systems are similar to one another if there are the same external environments around B ions in the host crystals. Being independent of the sign of the spin Hamiltonian parameter b(2)(0), it is increasingly close to zero along with structure parameter R increasing. Moreover, b(2)(0) is almost linear with the change of structure parameter theta. (C) 2009 Elsevier B.V. All rights reserved.
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