期刊
CHEMICAL PHYSICS LETTERS
卷 477, 期 1-3, 页码 80-84出版社
ELSEVIER
DOI: 10.1016/j.cplett.2009.06.055
关键词
-
资金
- Hungarian Scientific Research Fund [K75015]
A clinically important natural isoquinoline alkaloid, berberine, was used as a fluorescent probe to study the encapsulation of 1-alkyl-3-methylimidazolium (C(n)MIm(+)) type ionic liquids in 4-sulfonato-substituted calix[4] arene (SCX4) and calix[6]arene (SCX6) at pH 2. Addition of ionic liquids to the aqueous solution of berberine-SCXn inclusion complexes brought about considerable fluorescence intensity diminution due to the extrusion of berberine from the macrocycle into the aqueous phase by the competitive inclusion of CnMIm+ cation. The lengthening of the aliphatic side chain of the imidazolium moiety diminished the equilibrium constant of complexation with SCX4, but enhanced the stability of SCX6 complexes. Larger binding strength was found for SCX4. (c) 2009 Elsevier B.V. All rights reserved.
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