期刊
CHEMICAL PHYSICS LETTERS
卷 451, 期 4-6, 页码 198-203出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2007.12.016
关键词
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Calculations are presented for glycine-(H2O)(5) clusters, with glycine in canonical or zwitterionic form. The energies of zwitterionic conformers are calculated to be higher than the canonical ones by 2-4 kcal/mol. The dynamic pathways of canonical <--> zwitterion isomerization are presented, along with the magnitude of the activation barriers. We find that some of the zwitterionic glycine-(H2O)(5) clusters are kinetically stable for experimental observation due to considerable barriers (similar to 9 kcal/mol). (C) 2007 Elsevier B.V. All rights reserved.
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