期刊
CHEMICAL PHYSICS LETTERS
卷 450, 期 4-6, 页码 232-235出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2007.11.031
关键词
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Electron correlation can be the driving force for ultrafast charge migration. Using ab initio calculations this is demonstrated in the present paper for the first time as a consequence of ionizing the outer-valence shell. The example studied is 2-phenylethyl-N,N-dimethylamine (PENNA) on which exciting pump-probe measurements have been recently carried out. (C) 2007 Elsevier B.V. All rights reserved.
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