4.5 Article

Is size-consistency possible with density functional approximations?

期刊

CHEMICAL PHYSICS
卷 356, 期 1-3, 页码 91-97

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ELSEVIER
DOI: 10.1016/j.chemphys.2008.10.023

关键词

Size-consistency; Density functional theory; Range separated hybrids; Broken symmetry

资金

  1. [ANR-07-BLAN-0272]

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Density functional approximations do not provide size-consistent methods, contrary to what is commonly assumed in the literature. The violation is related to degeneracy. Two approaches are discussed to alleviate the problem: symmetry breaking and range separation. (C) 2008 Elsevier B.V. All rights reserved.

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