期刊
CHEMICAL PHYSICS
卷 348, 期 1-3, 页码 103-112出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chemphys.2008.02.035
关键词
mercury dimer; molecular rotational spectroscopy; rotational constants; bond lengths
Analysis of the rotational structure of the (57,0) vibrational band of the D1(u) <- X0(g)(+) transition in Hg-2 (natural abundance) is presented. From the analysis, the B-upsilon'=57, B-upsilon ''=0, B-c' and B-c '' rotational constants of the Hg-398(2), Hg-400(2), Hg-402(2), Hg-404(2) and Hg-406(2), as well as the R-c' = 2.715 angstrom and R-c '' = 3.605 angstrom bond lengths for the excited and ground electronic energy states involved in the transition are determined. (c) 2008 Elsevier B.V. All rights reserved.
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