期刊
CHEMICAL PHYSICS
卷 346, 期 1-3, 页码 115-131出版社
ELSEVIER
DOI: 10.1016/j.chemphys.2008.02.041
关键词
cyanoacetylene; rotational spectroscopy; infrared spectroscopy; excited states; global analysis; anharmonic resonances; linear molecule
The rotational spectrum of an enriched sample of HC C-C N-15 was measured in the range 8-27 GHz by means of a waveguide Fourier transform microwave spectrometer. New transitions were also measured in the millimetre- and submillimetre ranges. These measurements combined with the available rovibrational and rotational data [Fayt et al., J. Mol. Struct. 695-696 (2004) 295], with many newly assigned infrared bands, were used for a global rovibrational analysis of all vibrational states up to 1700 cm(-1). A full set of 243 molecular parameters for the modes upsilon(4)-upsilon(7) has been deduced. (C) 2008 Elsevier B.V. All rights reserved.
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