期刊
CHEMICAL GEOLOGY
卷 499, 期 -, 页码 126-137出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chemgeo.2018.09.020
关键词
Oxygen isotopes; SHRIMP ion microprobes; Olivine; Matrix effects; Nuasahi massif; Serpentinized dunite
资金
- Australian Research Council [DP110101599]
- Swiss National Science Foundation [SNSF 200021_166280]
In order to resolve inter-and intracrystalline oxygen isotopic heterogeneities in olivine crystals encountered in mantle peridotites, basaltic lavas, chondritic meteorites and metamorphic rocks, in situ techniques such as ion microprobes are needed. Accurate ion microprobe analysis requires not only well-characterised reference materials, but also calibration of the matrix bias for compositional variations within a given mineral. We investigated matrix bias effects related to Mg/Fe variations in olivine during in situ analysis of oxygen isotopes with sensitive high-resolution ion microprobe (SHRIMP) by analysing chemically homogenous olivine samples with forsterite contents in the range Fo(74)-Fo(100). The isotopic measurements were calibrated against San Carlos olivine (SCO; Fo(91)). The repeatability achieved for all samples was +/- 0.21-0.50 parts per thousand (standard deviation, SD, at 95% confidence level, c.l.) comparable to that of San Carlos olivine (+/- 0.31-0.48 parts per thousand, SD at 95% c.l.). A matrix bias up to similar to -2.0 parts per thousand was observed in olivine with forsterite content above 92 mol%, conversely to what has been reported for Cameca instruments. The relationship between the magnitude of matrix bias and fayalite content (mol%) is described by the quadratic function: Bias(Fa) = -0.0062 Fa(2) + 0.233 Fa - 1.60 The correction scheme for the matrix bias was applied to chemically zoned olivine crystals from a partly serpentinised dunite from the Archean Nuasahi massif (eastern India). Olivine cores (Fo(92)) preserve their typical mantle-like signature with a delta O-18 value of 5.16 +/- 0.30 parts per thousand (sigma at 95% c.l.). During a low temperature stage of serpentinisation, olivine transformed to lizardite(1) + brucite + magnetite. Olivine rims (Fo(98); delta O-18 = 1.92 +/- 0.60 parts per thousand, sigma at 95% c.l.) and the surrounding lizardite(2) (4.87 +/- 0.53 parts per thousand, sigma at 95% c.l.), formed during a later stage of rock-fluid interaction, are in isotopic equilibrium at similar to 405-430 degrees C, with a fluid having a delta O-18 of similar to 5.3-6.9 parts per thousand ?. Evolved seawater enriched in O-18 by isotopic exchange during infiltration could have been responsible for this later serpentinisation stage observed in the Nuasahi massif. The concomitant analysis of oxygen isotopes at the microscale in both olivine and serpentine represents a powerful tool to constrain the nature and source(s) of serpentinising fluid(s) as well as the temperature of serpentinisation.
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