期刊
CHEMICAL GEOLOGY
卷 266, 期 3-4, 页码 194-204出版社
ELSEVIER
DOI: 10.1016/j.chemgeo.2009.06.003
关键词
U-series; Hf; Nd; Sr; Ice cores; Sea salt
资金
- Swiss National Science Foundation
A new method for the radiogenic isotope (U-Th-Pa-Ra, Sr, Nd, Ho analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two clean-up columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for U-234/U-238 of 1%, Th-230/Th-232 of 1.5%, [Ra-228] of 9%, and Hf-176/Hf-171 of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: Sr-87/(86)sr of 50 ppm and Nd-143/Nd-144 of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and HE (C) 2009 Elsevier B.V. All rights reserved.
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