期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 12, 页码 3683-3687出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410053
关键词
cation exchange; core-shell nanocrystals; doped nanocrystals; phosphine ligands; semiconductors
资金
- National Natural Science Foundation [21322105, 91123001, 51372025, 91323301]
- Research Fund for the Doctoral Program of Higher Education of China [2011101120016]
- Program for New Century Excellent Talents in University [NCET-11-0793]
Phosphine-initiated cation exchange is a well-known inorganic chemistry reaction. In this work, different phosphines have been used to modulate the thermodynamic and kinetic parameters of the cation exchange reaction to synthesize complex semiconductor nanostructures. Besides preserving the original shape and size, phosphine-initiated cation exchange reactions show potential to precisely tune the crystallinity and composition of metal/semiconductor core-shell and doped nanocrystals. Furthermore, systematic studies on different phosphines and on the elementary reaction mechanisms have been performed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据