期刊
CHEMICAL ENGINEERING SCIENCE
卷 64, 期 23, 页码 5057-5065出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2009.08.011
关键词
Fixed bed reactor; Wave theory; Steam-iron process; Water gas-shift reaction
资金
- Fraunhofer-Gesellschaft
- Max Planck Society in Germany.
The cyclic water gas-shift reactor (CWGSR) is a cyclically operated fixed bed reactor for the removal of carbon monoxide from reformate gases. It is based on the repeated reduction of iron oxide by reformate gases and its subsequent oxidation by steam. To evaluate the thermodynamic limits of this reactor, we develop a model under the assumption of chemical equilibrium. For this purpose, we conduct a wave analysis which shows that the reactor behaviour is dominated by the movement of sharp reaction fronts. Depending on the positions of these fronts at cyclic steady state, five different operating regimes of the CWGSR can be identified. Besides the qualitative analysis of the regimes, the equilibrium model also offers a first quantitative analysis regarding the two performance parameters, i.e. fuel utilisation and product concentration. At 750 degrees C, a fuel utilisation of 55% can be achieved, and the molar hydrogen fraction in the product stream is up to 70%. The equilibrium model can be used for a first estimate of favourable design and operating parameters of the CWGSR. (C) 2009 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据