期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 8, 页码 2356-2360出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201409565
关键词
amination; asymmetric catalysis; dearomatization; naphthol; scandium
资金
- National Science Foundation of China [21222201, 21271147, 51202192]
- 1000 Youth Talents Plan
- Ministry of Education of China [20126101120011]
Catalytic asymmetric aminative dearomatization of 1-substituted 2-naphthols was successfully implemented with electrophilic azodicarboxylates under the catalysis of chiral Sc-III/pybox complexes. This intermolecular reaction represents a hitherto unknown enantioselective CN bond-forming process through direct dearomatization of phenolic compounds to generate chiral nitrogen-containing quaternary carbon stereocenters.
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