期刊
CHEMICAL ENGINEERING JOURNAL
卷 377, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.08.092
关键词
Hydrodesulfurization; Diesel; Structure manipulation; Co-Mo/mesoporous Al2O3; Industrial-scale
资金
- National Key Research and Development Program of China [2017YFB0306503]
- National Science Foundation of China [21606254]
- High-level Talent Innovation and Business Project of Dalian [2017RQ085]
- Open Project of State Key Laboratory of Chemical Engineering [SKL-ChE-18C04]
- Key Research and Development Plan of Shandong Province [2017GSF17126]
Ever-increasing concern on environmental impacts (e.g., sulfur pollution) by fossil fuels has triggered the research on hydrodesulfurization (HDS). In this work, Co-Mo nanoparticles were deposited on the mesoporous gamma-Al2O3 support with the addition of organic compound, and the physico-chemical properties of the catalysts (CoMo-C/mesoporous gamma-Al2O3) were then characterized by multi-techniques such as H-2-TPR, HRTEM, XPS, N-2 physisorption. It is found that the Co-Mo-C/mesoporous gamma-Al2O3 catalyst is easier to be reduced when organic compound is added, enhancing the sulfuration. This results in better dispersion of Co-Mo-S species and more CoMo-S II active sites, which significantly enhance diesel ultra-deep hydrodesulfurization activity. Furthermore, this novel catalyst was also tested for HDS reaction in a 3000 kt/a industrial-scale plant. Gratifyingly, this catalyst showed effective reduction of sulfur content from 9000 to less than 10 mu g/g and also high stability over 5000 h. The results are of great significance to the design and development of industrial HDS catalysts.
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