期刊
CHEMICAL ENGINEERING JOURNAL
卷 354, 期 -, 页码 172-181出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.08.024
关键词
Co3O4; Flower-like structure; Heteroatom doping; Anode; Lithium ion batteries
资金
- CAS Interdisciplinary Innovation Team, National Natural Science Foundation of China [21574043]
- Fundamental Research Funds for the Central Universities
Transition metal oxides-based electrode materials are currently under intensive research as anode candidates for next-generation lithium-ion batteries (LIBs) due to their environmental benignity, high capacity and natural abundance. Unfortunately, the intrinsically low conductivity and large structure change of metal oxide electrodes lead to their phase segregation and serious capacity decay, which severely restrict their practical application. In this work, we designed and fabricated a unique flower-like hybrid with Co3O4 nanoparticles decorated on nitrogen-doped carbon sheets (Co3O4/NC) through a combined carbonization and oxidation approach using novel cobalt-based metal-organic frameworks (MOFs) as precursor. The in-situ synthesis of Co3O4/NC from MOFs improves the combination between Co3O4 nanoparticles and nitrogen-doped carbonaceous substrate, ensures high structure stability and facilitates the electron and ion transport upon cycling. The as-synthesized Co3O4/NC exhibits a remarkable lithium storage performance with high reversible capacity (1145.1 mAh g(-1) after 100 cycles at 0.1 A g(-1)), superior rate capability (498.8 mAh g(-1) at 4 A g(-1)) and excellent long-term cycling stability (797.5 mAh g(-1) at 0.5 A g(-1) and 671.1 mAh g(-1) at 1 A g(-1) after 500 cycles), which outperforms those of most of Co3O4-based electrodes reported so far.
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