期刊
CHEMICAL ENGINEERING JOURNAL
卷 242, 期 -, 页码 96-101出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.12.018
关键词
TiO2-Pt; Aerogels; Photocatalytic hydrogen production; Ethanol reforming
资金
- Greece-Romania R&D cooperation program
- Romanian National Authority for Scientific Research, CNCS - UEFISCDI [PN-II-ID-PCE-2011-3-0442]
- National scholarship programme of the Slovak Republic for the support of mobility of students, PhD students, university teachers and researchers
TiO2-Pt aerogel composites have been synthesized by mixing sol-gel titania with Pt colloidal suspensions followed by supercritical drying. The highest specific surface achieved with these materials ranged between 550 and 600 m(2) g(-1) before annealing and stayed relatively high, i.e. 162 m(2) g(-1), after calcination. The concentration of Pt nanoparticles ranged between 0.3 and 1.0 wt.% while their size ranged between 5.75 and 6.5 nm. These composites were employed as photocatalysts for room-temperature photocatalytic reforming of ethanol and hydrogen production. The highest hydrogen production rate, 7.2 mmol H-2 h(-1) g(-1), was obtained in the case of the smallest and most concentrated metal nanoparticles underlying the importance of the number of active sites on the TiO2-Pt composites. This rate of hydrogen production is relatively high and reflects the relatively high specific surface of the employed photocatalysts. (C) 2013 Elsevier B.V. All rights reserved.
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