期刊
CHEMICAL ENGINEERING JOURNAL
卷 255, 期 -, 页码 471-482出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2014.04.098
关键词
Gum xanthan; Hydrogel nanocomposite; Malachite green; Adsorption isotherm; Adsorption kinetics
资金
- National Research Foundation (NRF), South Africa
- URC, University of Johannesburg, South Africa
Herein we report effective removal of malachite green (MG) from aqueous solution using gum xanthan (Gx)/Fe3O4 magnetic nanoparticles (MNPs) filled hydrogel nanocomposites. Gx-cl-P(AA-co-AAm)/Fe3O4 hydrogel nanocomposite was fabricated via incorporating Fe3O4 magnetic nanoparticles within the polymer matrix of the hydrogel of gum xanthan with co-polymer mixture of poly(acrylic acid-co-acrylamide). Maximum adsorption was observed in the solution of neutral pH with 0.2 g/L of Gx-cl-P(AA-co-AAm)/Fe3O4 hydrogel nanocomposite. Adsorption isotherm data was fitted with using five isotherm models like Langmuir, Freundlich, Temkin, Flory-Huggins and Dubinin-Kaganer-Radushkevich isothermal models and adsorption process was found to follow Langmuir isotherm model with maximum adsorption efficiency of 497.15 mg/g. Different adsorption kinetics models like pseudo first order, pseudo second order, Elovich, liquid particle diffusion and intra-particle diffusion models were applied to study the mechanism of adsorption. Moreover, adsorption kinetics data fitted well with pseudo second order rate model. Furthermore, thermodynamic studies demonstrate that adsorption process was endothermic and spontaneous. Moreover, adsorption-desorption studies suggests that Gx-cl-P(AA-co-AAm)/Fe3O4 hydrogel nanocomposite can be repeatedly used for the adsorption of MG. (C) 2014 Published by Elsevier B.V.
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