期刊
CHEMICAL ENGINEERING JOURNAL
卷 241, 期 -, 页码 327-335出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.11.012
关键词
Supercritical gasification; Hydrothermal; Hydrogen; Indole; Modeling
资金
- China Scholarship Council
- University of Michigan College of Engineering
- National Science Foundation [CBET-0755617]
- Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) [20090201110010]
We developed a quantitative kinetics model for the homogeneous decomposition and gasification of indole in supercritical water at 550-650 degrees C based on a reaction network with 17 separate reaction pathways. The model accurately describes the effects of time, temperature, and initial concentrations on the concentrations of intermediate products such as aniline, toluene, and benzene as well as the terminal gaseous products such as H-2, CH4, and CO2. Modeling revealed that three steps are most important for H2 production. Ring-opening of indole to form aniline is the fastest such step during the first few minutes at 600 degrees C, depletion of the large variety of gasifiable products dominates at times between 5 and 55 min, and water gas shift is the main H-2-producing reaction at longer times. The model also revealed that some of the potential pathways were kinetically insignificant at 600 degrees C. Such paths included methanation, gasification of benzene, steam reforming of indole, and formation of CO, CO2, and C2H6 from intermediate products. (C) 2013 Elsevier B.V. All rights reserved.
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