Film-form dye adsorbents of NiO: Synthesis, biological activity and application on dye sorption

Nowadays dye and agrichemical contaminations are becoming a severe environmental problem and subsequently a low-cost and effective method to eliminate the contaminations is becoming impending. In this study, a facile chemical precipitation method was developed to fabricate series of NiO coatings on porous alumina matrix. Scanning electron microscope, energy dispersive X-ray and powder X-ray diffraction confirmed the formation of meshy and crystalline NiO coatings. Moreover, the pore size, specific surface area and hydrophilic/hydrophobic properties could be adjusted by changing the matrix pore sizes. The biological assays revealed that NiO coatings could restrain the attachment of Aspergillus niger and exhibit a toxicity to the metabolism, proliferation and spread of NIH 3T3 cells. Additionally, the dye sorption capacity of coatings was investigated by employing Congo red as the model compound. The results indicated that the dye sorption capacity of coatings was affected by its surface features, including specific surface area and hydrophilic/hydrophobic properties. It could be concluded that film-form NiO products with special surface features had the potential as dye adsorbents for wastewater treatment. (C) 2012 Elsevier B.V. All rights reserved.