期刊
CHEMICAL ENGINEERING JOURNAL
卷 173, 期 3, 页码 866-872出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2011.08.037
关键词
CPO-27; MOFs; Ultrasound; Microwave; Kinetics; Lability
资金
- NRF
- MEST [R01-2007-0055718, 2008-0055718, 2009-0083696, 2010-0028783]
- National Research Foundation of Korea [과06B1508, 2007-0055718] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Isostructural MOFs such as CPO-27-Zn,CPO-27-Co and CPO-27-Ni were synthesized with US (ultrasound). MW (microwave) and CE (conventional electric) heating from the very similar reactant mixtures to understand the effect of the synthesis methods and metal ions on the synthesis rates and on the physicochemical properties of the obtained MOFs. The porosities (surface area and micropore volume) and synthesis rates both for nucleation and crystal growth are on the order of US > MW > CE synthesis. The crystal sizes are on the order of US < MW
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