期刊
CHEMICAL ENGINEERING JOURNAL
卷 161, 期 1-2, 页码 106-113出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2010.04.039
关键词
Ce-Ti oxide adsorbent; Sorption capacity; Sorption mechanism; As(V); As(III)
资金
- Sanyo Electric Co. Ltd.
- Program for New Century Excellent Talents in University
- Tsinghua University
Since As(V) and As(III) usually occur in groundwater simultaneously, the synthesis of novel adsorbents for both As(V) and As(III) removal is attractive. In this paper, a Ce-Ti hybrid oxide adsorbent with high sorption capacities for As(V) and As(III) was successfully prepared using a two-step reaction. Environmental scanning electron microscopy (ESEM) revealed that the Ce-Ti oxide adsorbent was composed of nanoparticles in the size range of 100-200 nm. Sorption isotherms show that the powdered adsorbent had high sorption capacity up to 7.5 mg/g for As(V) and 6.8 mg/g for As(III) at the equilibrium arsenic concentration of 10 mu g/L, higher than most reported adsorbents. The optimum adsorption capacity on the adsorbent was achieved at pH below 7 for As(V) and at neutral pH for As(III). Fourier transform infrared (FTIR) analysis indicated that the hydroxyl groups on the adsorbent surface were involved in arsenic adsorption, while X-ray photoelectron spectroscopy (XPS) provided further evidence for the involvement of hydroxyl groups in the sorption and the formation of monodentate and bidentate complexes on the adsorbent surface. (C) 2010 Elsevier BM. All rights reserved.
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